The asymmetric synthesis of (−)-pumiliotoxin C using tandem catalysis
نویسندگان
چکیده
منابع مشابه
Tandem rhodium catalysis: exploiting sulfoxides for asymmetric transition-metal catalysis.
Sulfoxides are uncommon substrates for transition-metal catalysis due to their propensity to inhibit catalyst turnover. In a collaborative effort with Ken Houk, we developed the first dynamic kinetic resolution (DKR) of allylic sulfoxides using asymmetric rhodium-catalyzed hydrogenation. A detailed mechanistic analysis of this transformation using both experimental and theoretical methods revea...
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15 صفحه اولColumn asymmetric catalysis for beta-lactam synthesis.
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ژورنال
عنوان ژورنال: Tetrahedron
سال: 2004
ISSN: 0040-4020
DOI: 10.1016/j.tet.2004.06.148